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Thiourea-Catalyzed Glycosylation: A Breakthrough in Stereoselective Synthesis of Oligosaccharides
Oligosaccharides are vital biomolecules that play an essential role in various biological functions. For studying biochemi...
A [CuII24] truncated octahedron and its [CuII8] building block
Reaction of CuCl2·2H2O with p-tert-butylthiacalix[4]arene (H4TC[4]A) affords a [CuII24] cage whose metallic skeleton ...
DBU-promoted cascade phosphorylation/cyclization for the synthesis of phosphorylated 3-aminoindoles
DBU-promoted cascade phosphorylation/cyclization for the synthesis of phosphorylated 3-aminoindoles A novel strategy of ca...
Recent development of azahelicenes showing circularly polarized luminescence
Recently, a variety of circularly polarized luminescence (CPL) dyes have been developed as next-generation chiroptical mat...
NiCo Alloy Particles Decorated on TiO2 Nanoarray as an Efficient Electrocatalyst for Nitrite Reduction to Ammonia
Electrocatalytic nitrite (NO2−) reduction (NO2−RR) is a potential environmentally friendly method for producing NH3 effici...
Direct and chemoselective transformation of cysteine to dehydroalanine on peptides
A direct method for the preparation of peptides containing a dehydroalanine residue was developed through the chemoselecti...
Novel Perovskite-Based Betavoltaic Cell: Dual Additive Strategy for Enhanced FAPbI3 α-phase Stability and Performance
By utilizing chlorine-based dual additives with perovskite film and radioactive isotopes of carbon nanoparticles/quantum d...
Phenylboronic acid-modified nanoparticles for cancer treatment
Phenylboronic acid (PBA) has emerged as a promising component in the design of functional nanomaterials for cancer treatme...
A Cascade Strategy for Vinyl Chloride-Substituted BODIPYs with Tunable Photophysical Properties
An efficient and transition-metal-free method for the synthesis of unprecedented vinyl chloride-substituted BODIPYs has be...
Designing NNO-Manganese Complex Overcoming Steric Constraints in (De)hydrogenative Coupling
Herein, we have developed a NNO-manganese complex featuring a less congested metal-ligand cooperative environment, which e...
Regulated TiO2@NC@ZCS Photocatalyst for Efficient Hydrogen Evolution: Insights into the Role of Carbon Layer Positioning
In this study, a TiO2@NC@ZCS ternary photocatalyst with a well-defined hexahedral morphology was synthesized via MOF-deriv...
Heterocycles in reactions with boradigermaallyl
Reactions of boradigermaallyl, which can also be regarded as a chloroborylene stabilzed by two germylene donors, with thio...
Correction: Interstitial and substitutional doping of Mn2+ in 2D PEA2PbBr4 and BA2PbBr4 perovskites
Correction for ‘Interstitial and substitutional doping of Mn2+ in 2D PEA2PbBr4 and BA2PbBr4 perovskites’ by Udara M. Kurup...
Green synthesis of ultra-bright Cs3MnBr5 films by CVD method
In this study, we successfully synthesized Cs3MnBr5 films via vapor deposition for the first time using CsBr and MnBr2 raw...
One-pot Transfer Hydrogenation and Reductive Amination of Polyenals
The efficient preparation of long-chain amines via a one-step transfer-hydrogenation/reductive-amination reaction (THRA) o...
Ring-opening silylation of N-arylindoles via endocyclic C−N bond cleavage triggered by silylboranes
The cleavage of heteroaromatic endocyclic carbon-heteroatom bonds to assemble C-Si bonds is scarce. Here, we demonstrate a...
Surface Properties of Carbon Nitride Materials Used in Photocatalytic Systems for Energy and Environmental Applications
The use of photocatalytic systems involving semiconductor materials for environmental and energy applications, such as wat...
Selective 17O-Labeling of Silica
The addition of 17OH2 to silica at room temperature leads to spontaneous hydroxyl oxygen exchange and the selective isotop...
Syn-1,2-Diaminobenzocyclobutenes from [2+2] cycloaddition of 2-imidazolones with arynes
Formal [2+2] cycloaddition of arynes with 2-imidazolones affords syn-1,2-diaminobenzocyclobutenes. The transformation can ...
An organic-inorganic hybrid perovskite material [Me3NCMe3]GaCl4 exhibits a two-step off-on-off SHG response with large temperature interval
Reaction of a quaternary ammonium salt with GaCl3 in concentrated HCl aqueous solution led to an organic-inorganic hybrid ...
An octahedral coordination cage with six Fe(III) centers as a T1 MRI probe
The incorporation of multiple Fe(III) centers bridged by rigid ligands into a coordination cage represents a powerful appr...
Promoting exchange coupling in (CpiPr5)2Gd2X3 complexes
Introducing magnetic coupling between lanthanide ions has been shown to yield better-performing single-molecule magnets (S...
Photoswitchable TCB-2 for Control of the 5-HT2A Receptor and Analysis of Biased Agonism
Therapies that target the serotonin 2A receptor (5-HT2AR) are promising. However, probes are needed to better understand t...
Deoxygenation of Allyl Arylsulfones to Allyl Arylthioethers via “Cut-Sew” Strategy: Phosphines as Bifunctional Reagents
Herein we disclosed a protocol for the deoxygenation of allyl arylsulfones to access the corresponding thioethers under ph...
Fullerene as a Probe Molecule for Single-Atom Oxygen Reduction Electrocatalysts
Fullerenes interact positively with many metal-based catalysts via intense electron transfer. Yet, we here reveal that C60...
Efficient Co-Upcycling of Glycerol and CO2 into Valuable Products Enabled by a Bifunctional Ru-Complex Catalyst
Glycerol and CO2 are largely produced as by-products in modern industry. Herein, three Ru complexes bearing air- and water...
Photoinduced 1,5-HAT-enabled 1,7-hydrosulfonylation of allylic ethers and amides
Herein, we reported a photoinduced 1,7-hydrosulfonylation of allylic ethers and amides via sequential Pd-mediated 1,5-HAT ...
Identification and detection of conserved G-quadruplex in monkeypox virus using conformation specific fluorogenic probe
Identifying distinct noncanonical structures in pathogenic genomes is crucial for developing new diagnostic tools. This st...