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One-pot Transfer Hydrogenation and Reductive Amination of Polyenals
The efficient preparation of long-chain amines via a one-step transfer-hydrogenation/reductive-amination reaction (THRA) o...
Ring-opening silylation of N-arylindoles via endocyclic C−N bond cleavage triggered by silylboranes
The cleavage of heteroaromatic endocyclic carbon-heteroatom bonds to assemble C-Si bonds is scarce. Here, we demonstrate a...
Collectively Optimizing Pt-O Bond and Morphology Engineering of Structurally Ordered Pt3Zn Intermetallic for High-efficient Zinc-air Devices
We report an ordered Pt3Zn intermetallic of optimizing Pt-O bond and featuring unique nanocubes (NCs) morphology for high-...
Surface Properties of Carbon Nitride Materials Used in Photocatalytic Systems for Energy and Environmental Applications
The use of photocatalytic systems involving semiconductor materials for environmental and energy applications, such as wat...
Selective 17O-Labeling of Silica
The addition of 17OH2 to silica at room temperature leads to spontaneous hydroxyl oxygen exchange and the selective isotop...
Syn-1,2-Diaminobenzocyclobutenes from [2+2] cycloaddition of 2-imidazolones with arynes
Formal [2+2] cycloaddition of arynes with 2-imidazolones affords syn-1,2-diaminobenzocyclobutenes. The transformation can ...
An organic-inorganic hybrid perovskite material [Me3NCMe3]GaCl4 exhibits a two-step off-on-off SHG response with large temperature interval
Reaction of a quaternary ammonium salt with GaCl3 in concentrated HCl aqueous solution led to an organic-inorganic hybrid ...
An octahedral coordination cage with six Fe(III) centers as a T1 MRI probe
The incorporation of multiple Fe(III) centers bridged by rigid ligands into a coordination cage represents a powerful appr...
Promoting exchange coupling in (CpiPr5)2Gd2X3 complexes
Introducing magnetic coupling between lanthanide ions has been shown to yield better-performing single-molecule magnets (S...
Photoswitchable TCB-2 for Control of the 5-HT2A Receptor and Analysis of Biased Agonism
Therapies that target the serotonin 2A receptor (5-HT2AR) are promising. However, probes are needed to better understand t...
Deoxygenation of Allyl Arylsulfones to Allyl Arylthioethers via “Cut-Sew” Strategy: Phosphines as Bifunctional Reagents
Herein we disclosed a protocol for the deoxygenation of allyl arylsulfones to access the corresponding thioethers under ph...
Fullerene as a Probe Molecule for Single-Atom Oxygen Reduction Electrocatalysts
Fullerenes interact positively with many metal-based catalysts via intense electron transfer. Yet, we here reveal that C60...
Efficient Co-Upcycling of Glycerol and CO2 into Valuable Products Enabled by a Bifunctional Ru-Complex Catalyst
Glycerol and CO2 are largely produced as by-products in modern industry. Herein, three Ru complexes bearing air- and water...
Photoinduced 1,5-HAT-enabled 1,7-hydrosulfonylation of allylic ethers and amides
Herein, we reported a photoinduced 1,7-hydrosulfonylation of allylic ethers and amides via sequential Pd-mediated 1,5-HAT ...
Identification and detection of conserved G-quadruplex in monkeypox virus using conformation specific fluorogenic probe
Identifying distinct noncanonical structures in pathogenic genomes is crucial for developing new diagnostic tools. This st...
Asymmetric electrophilic functionalization of amino-substituted heteroaromatic compounds: a convenient tool for the enantioselective synthesis of nitrogen heterocycles.
The catalytic asymmetric electrophilic functionalization of the less reactive N-heteroaromatic compounds has been reported...
Correction: A closer look at ligand specificity for cellular activation of NOD2 with synthetic muramyl dipeptide analogues
Correction for ‘A closer look at ligand specificity for cellular activation of NOD2 with synthetic muramyl dipeptide analo...
Electrochemical detection of glutathione based on accelerated CRISPR/Cas12a trans-cleavage with MnO2 nanosheets
CRISPR/Cas12a system is accelerated by glutathione-mediated reduction of MnO2 nanosheets. By monitoring trans-cleavage eve...
Emerging Pt-based intermetallic nanoparticles for oxygen reduction reaction
The advancement of highly efficient and enduring platinum (Pt)-based electrocatalysts for the oxygen reduction reaction (O...
Sulphur-induced structural rearrangement in the self-sensitization photo-oxidation behaviour of phenothiazine-imidazole molecules
A green photo-oxidation reaction was discovered in which the imidazole ring is oxidized and rearranged to generate imidazo...
DMF as amine source: iron-catalyzed cyclization of 2H-azirines to imidazoles
A novel method has been developed for the synthesis of 1-methyl-4,5-diaryl-1H-imidazoles through Fe(II)-catalyzed cyclizat...
Iron content in aerosol particles and its impact on atmospheric chemistry
Atmospheric aerosol effects on ecological and human health remain uncertain due to their highly complex and evolving natur...
NIR phosphorescence from decatungstate anions allows the conclusive characterization of its elusive excited triplet behaviour and kinetics
The characterization of the triplet state of decatungstate (3DT*) and its NIR phosphorescence with lifetimes ~100 ns in ac...
All-element recovery and regeneration of mixed LiNixCoyMn1-x-yO2/LiFePO4 cathode materials by synergistic redox processes
Given the rising lithium-ion battery retirement trend, there is a pressing need for a sustainable, and industrially viable...
Structure Prediction from Spectra amidst Dynamical Heterogeneity in Melanin
Melanin is a biopolymer pigment that plays a central role in skin photoprotection. Its extensive chemical and dynamical he...
Layer-by-layer designer nanoarchitectonics for physical and chemical communications in functional materials
Nanoarchitectonics, as a post-nanotechnology concept, constructs functional materials and structures using nanounits of at...
Recent Advances in Phase Change Materials for Thermal Energy Storage
Efficient storage of thermal energy can be greatly enhanced by the use of phase change materials (PCMs). The selection or ...
Accelerating Electrosynthesis of Ammonia from Nitrates Using Coupled NiO/Cu Nanocomposites
Herein, we report a nanocomposite electrocatalyst with coupled Cu and NiO prepared by co-electrodeposition. The optimal ra...
Controllable fabrication of well-shaped PMBA@CsPbBr3 nanoparticles for highly sensitive HCl and HBr detection
We report a facile two-step strategy to construct well-shaped PMBA@CsPbBr3 nanoparticles by combining in-situ adsorption a...
Ce-regulating defect and morphology engineering for efficient enhancing piezocatalytic performances of BiOBr
Cerium-doped bismuth oxybromide (1%, 5% and 10% Ce-BiOBr) piezocatalysts were synthesized. The piezocatalytic activity was...
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