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Advanced spectroscopic studies of (PPh4)2[Co(N3)4], a field-induced single-ion magnet
High-spin CoII complex (PPh4)2[Co(N3)4] (Co-N3) has been investigated using advanced spectroscopic techniques [far-IR magn...
Enhancement of Fenton-like degradation organic dyes performance by constructing Ni substitution at B-site for LaCoxNi1-xO3 perovskite catalysts
Perovskite-type catalysts show a good prospect in the field of pollutant degradation. Bimetallic doping can regulate the s...
Photoinduced formation of singlet oxygen with PCBM-Pd polymer in solution and at the surface
The polymeric material of PCBM-Pd was prepared using both electrochemical and chemical synthesis. The electrochemical form...
Fabrication of three-dimensionally ordered mesoporous zirconia using nanoporous carbon as a scaffold
Zirconia exhibits important properties such as catalytic activity, ionic conductivity, and dielectric properties. Nanoporo...
Mg/Al LDO microspheres with high surface area for efficient tetracycline hydrochloride removal from water
Mg/Al layered double oxide (Mg/Al LDO) microspheres with a high specific surface area (221.69 m2·g-1) were synthesize...
Harnessing Co/Mo Dual-Atom Synergy on N, P-Carbon Nanofibers for Superior Bifunctional Water Splitting
Developing cost-effective, active, and durable bifunctional electrocatalysts for the hydrogen evolution reaction (HER) and...
Magnetic superexchange couplings in doubly bis(2-pyridyl)pyrazolato-bridged dinuclear copper(II) complexes
The solvothermal reaction of CuCl2·2H2O with 3,5-bis(2-pyridyl)pyrazole (Hbpypz) in a methanol/water mixed solvent pr...
Preparation of black nano-titanium dioxide by B2O3 sealed magnesium weak reduction method and kinetic analysis
In this paper, the preparation of black titanium dioxide by surface weak reduction by Mg of white titanium dioxide and its...
Preparation and characterization of rose bengal modified chitosan/ polyethylene oxide nanocomposite membranes with Photodynamic antimicrobial properties
To address the challenge of antibiotic resistance and cross-infection from microorganisms, chitosan (CS) was covalently bo...
Selective Oxidative Cleavage of Epoxides to Aldehydes by Chitin Quaternary Ammonium Phosphotungstate as a Recycle Catalyst
The selective cleavage oxidation of epoxide represents a promising strategy for generating value-added chemicals such as a...
Synergistic Catalysis: Ce(IV)-Driven Oxidation Reactions Facilitated by Micellar Composites
The catalytic behaviour of polymer–surfactant (PS) composites has gained significant interest due to their ability to infl...
Substituent effect on the solvatochromic behaviour of benzoimidazole based Donor-Acceptor type fluorescent molecules
In this study a series of donor-acceptor type fluorescent molecules were synthesised and there photophysical properties we...
Synthesis, antiproliferative activity, ADMET, molecular docking, molecular dynamics simulation, and DFT study for coumarin-based 1,5-benzothiazepines
Some α,β-unsaturated ketones 5a-h were prepared from 3-acetyl-4-hydroxycoumarin and (hetero)aromatic aldehydes with yields...
Dissipative formation of a transient foldaxane with a fuel-like thread
Transient assemblies generated by fuel consumption biomacromolecules are essential for biological processes. Although arti...
Photoredox β-C(sp3)-H Heteroarylation of o-Iodoaryl-alkan-1-ones with Heteroarenes via HAT and Dual C-H Functionalizations
A synthetically useful method for the formal β-heteroarylation of ketones via an iodoarene-directed photoredox remote C(sp...
Dual-State Emission of Pyrazolyl-Pyrrolo[3,4-b]pyridin-5-ones via Excited-State Intramolecular Proton Transfer (ESIPT): Multicomponent Synthesis and Optical Characterization
The dual-state emission (DSE) phenomenon has become crucial for developing dual-state emission luminogens (DSEgens) that e...
Recent advances in the synthesis of nitrogen heterocycles via Rh(III)-catalyzed chelation-assisted C-H activation/annulation with diazo compounds
Diazo compounds are a class of readily available and versatile reagents in modern organic synthesis that have been used as...
Mechanophoric hydrogels: when mechanical stress produces useful responses
Mechanophoric hydrogels undergo visible color changes or alterations in optical properties in response to mechanical stimu...
Core-Extended Nonastarazines Featuring Diverse Arm Configurations via One-Pot Sequential Reactions
This article presents the successful synthesis of a novel series of core-extended quasi-planar nonastarazine (NSA) derivat...
Photoredox-Catalyzed Generation of α-Carbonyl Carbocations: General Access to α-Tertiary Amino Acid Derivatives
α-Carbonyl carbocations, serving as the umpolung forms of the synthetically fundamental α-carbonyl carbanions, are highly ...
Cycloisomerization of 7-En-2-yn-1-ones to Bicyclo[3.1.0]hexanes Using Electrophilic Fluorination or Chlorination Agents
In contrast to the π-electrophilic transition metal-catalyzed cycloisomerization of enynes, systematic studies on the reac...
Biocatalytic atroposelective synthesis of heterobiaryls and heterobiaryl N-oxides via dynamic kinetic resolution
Heterobiaryl and heterobiaryl N-oxide atropisomers are important scaffolds in various chiral ligands, organocatalysts, and...
In situ generated cobalt(I) catalyst for the efficient synthesis of novel pyridines: Revisiting the mechanism of [2+2+2] cycloadditions
The [2+2+2] cycloaddition of alkynes and nitriles is an efficient and atom-economic method for the synthesis of pyridines....
Organocatalytic Asymmetric Desymmetrization of Cyclopentene-1,3-diones via Formal Diaza-ene Reaction with Donor–Acceptor Hydrazones
Herein we disclose a catalytic asymmetric desymmetrization of cyclopentene-1,3-diones via formal diaza-ene reaction/tautom...
A Protodefluorinated Selectfluor® Heteroaggregate Photoinduces Direct C(sp3)−H Fluorinations Without Photocatalyst
Herein, we uncover a hitherto hidden role of H-TEDA(BF4)2 – a cheap, stable, recoverable by-product of radical C(sp3)–H fl...
Deoxygenative ortho-Benzylation of Aryl Iodides with Benzyl Alcohol via Palladium/Norbornene Cooperative Catalysis
Herein, we demonstrate a robust palladium/norbornene-catalyzed deoxygenative ortho-benzylation of aryl iodides with non-de...
Facile synthesis of novel Ni-BDC-NH2/Au NPs SERS substrates with synergistic enhancement effects for high-performance detection
Substrate materials with high sensitivity and good reproducibility are highly desirable for the practical applications of ...
Ag-nanoplates decorated cavity-nanorod array SERS substrate for trace detection of PCB-77
We reported the fabrication of a substrate with cavity-nanorod and decorated by Ag-nanoplates (C-NR@Ag). The cavities on t...
Qualitative and quantitative analysis of metronidazole formulations using a low-cost near infrared transmission spectrophotometer and chemometric tools
For an effective drug quality control and detection of falsified and substandard medicines in developing countries, there ...
Robust PET-Based Chiral Schiff Base Molecular Probe for Recognition of Hg2+ and Pb2+ and Its Live Cell Imaging
A new salen-based chiral Schiff base, 6,6'-((1E,1'E)-((1R,2R)-cyclohexane-1,2-diylbis(azanylylidene))bis(methanyly...
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