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Organosilanes as synthetic precursors for oligosiloxanes and phenylsilica spheres
The study describes the synthesis of disiloxanes, R3SiOSiR3, tetraorganodisiloxanes-1,3-diols, (RR1SiOH)2O, and silanol, t...
Theoretical Prediction of Negative Thermal Expansion in Cubic VF3
Designing and discovering negative thermal expansion materials is import in precisely controlled thermal expansion devices...
Synthesis, anticancer activity and molecular simulation of N-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)thioureas containing pyrimidine ring
A series of thioureas 7a-k containing pyrimidine and D-glucose moiety have been synthesized through the reaction between s...
Isolation and characterization of novel degradation products in Fenoverine by LC-QTOF-MS/MS, LC-MSn and 2D-NMR
This study investigates the degradation profile of Fenoverine (FEN), an antispasmodic drug, following the International Co...
Photocatalytic degradation of tetracycline hydrochloride by BiVO4/MIL-88B(Fe) heterojunction
A type II heterostructured BiVO4/MIL-88B(Fe) composite was successfully synthesised for the photocatalytic degradation of ...
A Novel In-Syringe Cloud Point Extraction Method for the Determination of Cadmium and Lead in Human Hair Samples
The measurement of contaminant elements, especially cadmium and lead, in biological samples typically requires time-consum...
18 kDa TSPO specific ligand based polymeric nanoformulation: Synthesis, computational and biological studies
The 18 kDa Translocator protein (TSPO) serves as a promising target for drug delivery and imaging applications. In this in...
Effect of ammonia addition on dispersion and activity of supported copper species on porous silica-alumina hollow spheres for catalytic decomposition of nitrous oxide
This work investigated influence of ammonia addition in the immersion process of active species on dispersion and activity...
Tailoring of novel morpholine-sulphonamide linked thiazole moiety as dual targeting DHFR/DNA gyrase inhibitors: Synthesis, antimicrobial, antibiofilm activities and DFT with molecular modelling studies
Herein, the chemical synthesis of new thiazoles-based benzenesulfonamide-linked morpholine 4a,b–7 via late-stage thiazolat...
Evaluation of adsorption and degradation performance of lanthanum modified mesoporous carbon nitride composite materials for tetracycline wastewater
The lanthanum modified mesoporous graphite nitride carbon composites (La-g-C3N4) were synthesized using a thermal shrinkag...
Enhanced photocatalytic activity of carbon nitride nanosheets with alkali metal ion doping
Photocatalytic degradation of pollutants is one of the most promising strategies for addressing environmental issues assoc...
Ultrasound-assisted ionic liquid-mediated green method for synthesis of 1,3-diphenylpyrazole-based spirooxindolopyrrolizidines, their anti-tubercular activity, molecular docking study and ADME predictions
The aim of the study is to develop the synthesis of a novel series of potent anti-tubercular (anti-TB) activity of 1,3-dip...
Sulfonic groups modified carbon nanotubes: the decorative strategy for enhancing the performance of lithium-sulfur batteries
Porous carbon nanotubes can not only provide a large surface area for anchoring sulfur and restraining polysulfides, but a...
Effect of Functionalized Multiwalled Carbon Nanotubes on Mechanical, Swelling and Viscoelastic Properties on Gum ghatti-cl-poly(NIPAm) Hydrogels
The present work involves the Gum ghatti-cl-poly(NIPAm)/-o-MWCNT (GGNIPACNT) hydrogels via free radical polymerization tec...
Self-Sacrificial templated-directed synthesis of ultrathin 0D/2D FeNi3-NC/NiFeOx Schottky junction as hydrogen evolution reaction electrode for alkaline seawater electrolysis
Seawater, a plentiful natural resource, is promising for hydrogen production compared to traditional electrocatalytic meth...
Electrodeposited Ni-Fe alloy a cost-effective material for harnessing hydrogen via oxygen evolution and urea oxidation reaction
Electrochemical energy conversion for hydrogen production is a crucial method to address global energy demand. Here, a cos...
An aerobic copper-catalyzed multi-component reaction strategy for N',N'-diaryl acylhydrazines synthesis: reactions and mechanism
A sequential multi-component reaction has been achieved via aerobic copper-catalyzed intermolecular C-N/C-O bonds cascade ...
Enantioselective synthesis of chiral BCPs
Bicyclo[1.1.1]pentanes (BCPs) have emerged as an interesting scaffold in drug design. This strained molecule can act as bi...
Metal-free photocatalytic homo- and cross dimerization of α-hydroxy ketones via dual C(sp3)-H functionalization: synthesis of 2,3-dihydroxy-1,4-butanediones
The dimerization reactions of α-hydroxy ketones in the α-carbon site have been realized by visible light photocatalysis in...
Electrochemistry multicomponent cascade annulation and functionalization reaction to enable C(sp3)-H trifluoromethylation
Herein, we describe a novel electrochemistry facilitated one-pot multicomponent cascade annulation and bi-functionalizatio...
Dithiocarbamate mediated thioamidation via C-C single bond cleavage of styrene: Study of the protocol on decarbonylative and decarboxylative thioamidations
Dithiocarbamate salts have been explored in a novel C-C thioamidation of styrene in presence of ammonium persulfate and mo...
Highly regio- and stereoselective bromochlorination and bromoazidation of 1,3-dienes
A substrate-induced strategy for the bromochlorination and bromoazidation of diverse 1,3-dienes has been reported. This pr...
Obscurinin A, a unique Lycopodium alkaloid possessing an 8/6/6/6/5 pentacyclic system isolated from Lycopodium obscurum L.
Obscurinin A (1), an unprecedented Lycopodium alkaloid featuring an 8/6/6/6/5 ring system, was isolated from the methanol ...
Gold-catalyzed cyclization/nucleophilic addition reaction of o-alkynylanilines with ynamides: stereoselective synthesis of 3-vinylindoles
The functionalized 3-vinylindoles were obtained through the cyclization/nucleophilic addition of ynamides and o-alkynylani...
Palladium-catalyzed [6+4] cycloaddition with π-allyl all-carbon 1,6-dipole for the synthesis of ten-membered heterocycles
This paper presents the design and synthesis of a novel α,α-diester-δ-vinylvalerolactone, utilized as a new all-carbon dip...
Catalyst-free photoarylation reactions promoted by visible light
The use of visible light as a means of promoting chemical transformations offers a more sustainable and efficient alternat...
Experimental and Computational Studies on the Palladium-catalyzed Intramolecular Dearomatization, Electrophilic Addition, Intermolecular Coupling Sequence
An unprecedented Pd-catalyzed highly stereoselective synthetic strategy for the construction of a broad spectrum of polycy...
Recent Advances on Hydrogen Atom Transfer Induced C(sp3)-H Functionalizations Initiated by Radical Addition to Alkynes
Direct functionalization of C(sp3)-H bonds represents a pivotal objective in the realm of synthetic chemistry. However, th...
Distal Iodine Migration of Arylalkynes via Cyclic Monoaryliodonium Salts
Disclosed herein is a novel protocol for the synthesis of cyclic monoaryliodonium salts (CMAIs) from readily available iod...
Nickel-Catalyzed Reductive 1,1-Diarylation of Unactivated Alkenes with Aryl Iodide
In this article, we wish to present a nickel-catalyzed reductive 1,1-diarylation reaction of unactivated alkenes with aryl...
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