Herein, we reported a photoinduced 1,7-hydrosulfonylation of allylic ethers and amides via sequential Pd-mediated 1,5-HAT process and Pd-catalyzed allylic nucleophilic attack of arylsulfonates. This rationally designed synthetic protocol allows for facile construction of a series of structurally novel allylic sulfonated scaffolds, which features mild conditions, cheap and readily available raw materials and functional group compatibility.

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