Lutz, J.-F. Sequence-controlled polymerizations: the next Holy Grail in polymer science? Polym. Chem. 1, 55 (2010).

Article  CAS  Google Scholar 

Woolfson, D. N. The design of coiled-coil structures and assemblies. Adv. Protein Chem. 70, 79–112 (2005).

Article  CAS  PubMed  Google Scholar 

Zakeri, B. et al. Peptide tag forming a rapid covalent bond to a protein, through engineering a bacterial adhesin. Proc. Natl Acad. Sci. USA 109, E690–E697 (2012).

Article  CAS  PubMed  PubMed Central  Google Scholar 

Mirkin, C. A., Letsinger, R. L., Mucic, R. C. & Storhoff, J. J. A DNA-based method for rationally assembling nanoparticles into macroscopic materials. Nature 382, 607–609 (1996).

Article  CAS  PubMed  Google Scholar 

Park, S.-J., Lazarides, A. A., Storhoff, J. J., Pesce, L. & Mirkin, C. A. The structural characterization of oligonucleotide-modified gold nanoparticle networks formed by DNA hybridization. J. Phys. Chem. A 18, 12375–12380 (2004).

Google Scholar 

Gartner, Z. J. & Liu, D. R. The generality of DNA-templated synthesis as a basis for evolving non-natural small molecules. J. Am. Chem. Soc. 123, 6961–6963 (2001).

Article  CAS  PubMed  PubMed Central  Google Scholar 

Gartner, Z. J. et al. DNA-templated organic synthesis and selection of a library of macrocycles. Science 305, 1601–1605 (2004).

Article  CAS  PubMed  PubMed Central  Google Scholar 

Breaker, R. R. & Joyce, G. F. A DNA enzyme that cleaves RNA. Chem. Biol. 1, 223–229 (1994).

Article  CAS  PubMed  Google Scholar 

Li, Y. & Sen, D. A catalytic DNA for porphyrin metallation. Nat. Struct. Biol. 3, 743–747 (1996).

Article  CAS  PubMed  Google Scholar 

Chandra, M. & Silverman, S. K. DNA and RNA can be equally efficient catalysts for carbon-carbon bond formation. J. Am. Chem. Soc. 130, 2936–2937 (2008).

Article  CAS  PubMed  Google Scholar 

Macfarlane, R. J. et al. Nanoparticle superlattice engineering with DNA. Science 334, 204–208 (2011).

Article  CAS  PubMed  Google Scholar 

Rothemund, P. W. K. Folding DNA to create nanoscale shapes and patterns. Nature 440, 297–302 (2006).

Article  CAS  PubMed  Google Scholar 

Mathur, D. & Henderson, E. R. Complex DNA nanostructures from oligonucleotide ensembles. ACS Synth. Biol. 2, 180–185 (2013).

Article  CAS  PubMed  Google Scholar 

Nie, Z., Wang, P., Tian, C. & Mao, C. Synchronization of two assembly processes to build responsive DNA nanostructures. Angew. Chem. Int. Edn Engl. 53, 8402–8405 (2014).

Article  CAS  Google Scholar 

Merrifield, R. B. Solid phase peptide synthesis. The synthesis of a tetrapeptide. J. Am. Chem. Soc. 85, 2149–2154 (1963).

Article  CAS  Google Scholar 

Letsinger, R. L. & Mahadevan, V. Oligonucleotide synthesis on a polymer support. J. Am. Chem. Soc. 87, 3256–3257 (1965).

Article  Google Scholar 

Al Ouahabi, A., Charles, L. & Lutz, J.-F. O. Synthesis of non-natural sequence-encoded polymers using phosphoramidite chemistry. J. Am. Chem. Soc. 137, 5629–5635 (2015).

Article  CAS  PubMed  Google Scholar 

Hill, S. A., Gerke, C. & Hartmann, L. Recent developments in solid-phase strategies towards synthetic, sequence-defined macromolecules. Chem. Asian J. 13, 3611–3622 (2018).

Article  CAS  PubMed  Google Scholar 

Strom, K. R. & Szostak, J. W. Solid-phase synthesis of sequence-defined informational oligomers. J. Org. Chem. 85, 13929–13938 (2020).

Article  CAS  PubMed  PubMed Central  Google Scholar 

Knight, A. S. et al. Sequence programmable peptoid polymers for diverse materials applications. Adv. Mater. 27, 5665–5691 (2015).

Article  CAS  PubMed  Google Scholar 

Ferrand, Y. & Huc, I. Designing helical molecular capsules based on folded aromatic amide oligomers. Acc. Chem. Res. 51, 970–977 (2018).

Article  CAS  PubMed  Google Scholar 

Reuther, J. F. et al. Dynamic covalent chemistry enables formation of antimicrobial peptide quaternary assemblies in a completely abiotic manner. Nat. Chem. 10, 45–50 (2018).

Article  CAS  Google Scholar 

Binauld, S., Damiron, D., Connal, L. A., Hawker, C. J. & Drockenmuller, E. Precise synthesis of molecularly defined oligomers and polymers by orthogonal iterative divergent/convergent approaches. Macromol. Rapid Commun. 32, 147–168 (2011).

Article  CAS  PubMed  Google Scholar 

Barnes, J. C. et al. Iterative exponential growth of stereo- and sequence-controlled polymers. Nat. Chem. 7, 810–815 (2015).

Article  CAS  PubMed  Google Scholar 

Takizawa, K., Tang, C. & Hawker, C. J. Molecularly defined caprolactone oligomers and polymers: synthesis and characterization. J. Am. Chem. Soc. 130, 1718–1726 (2008).

Article  CAS  PubMed  Google Scholar 

Leibfarth, F. A., Johnson, J. A. & Jamison, T. F. Scalable synthesis of sequence-defined, unimolecular macromolecules by flow-IEG. Proc. Natl Acad. Sci. USA 112, 10617–10622 (2015).

Article  CAS  PubMed  PubMed Central  Google Scholar 

Lee, J. M. et al. Semiautomated synthesis of sequence-defined polymers for information storage. Sci. Adv. 8, 8614 (2022).

Article  Google Scholar 

Lee, J. M. et al. High-density information storage in an absolutely defined aperiodic sequence of monodisperse copolyester. Nat. Commun. 11, 56 (2020).

Article  CAS  PubMed  PubMed Central  Google Scholar 

Laurent, Q., Sakai, N. & Matile, S. An orthogonal dynamic covalent chemistry tool for ring-opening polymerization of cyclic oligochalcogenides on detachable helical peptide templates. Chem. Eur. J. 28, e202200785 (2022).

Article  CAS  PubMed  Google Scholar 

Núñez-Villanueva, D. & Hunter, C. A. Replication of a synthetic oligomer using chameleon base-pairs. Chem. Commun. 58, 11005–11008 (2022).

Article  Google Scholar 

Núñez-Villanueva, D. & Hunter, C. A. H-bond templated oligomer synthesis using a covalent primer. J. Am. Chem. Soc. 144, 17307–17316 (2022).

Article  PubMed  PubMed Central  Google Scholar 

Rosenbaum, D. M. & Liu, D. R. Efficient and sequence-specific DNA-templated polymerization of peptide nucleic acid aldehydes. J. Am. Chem. Soc. 125, 13924–13925 (2003).

Article  CAS  PubMed  Google Scholar 

Xue, C. & Luo, F.-T. Efficient and rapid synthesis of oligo(p-phenylenevinylene) via iterative coherent approach. J. Org. Chem. 68, 4417–4421 (2003).

Article  CAS  PubMed  Google Scholar 

Hoff, E. A., De Hoe, G. X., Mulvaney, C. M., Hillmyer, M. A. & Alabi, C. A. Thiol−ene networks from sequence-defined polyurethane macromers. J. Am. Chem. Soc. 142, 6729–6736 (2020).

Article  CAS  PubMed  Google Scholar 

Brown, J. S. et al. Synthesis and solution-phase characterization of sulfonated oligothioetheramides. Macromolecules 50, 43 (2017).

Article  Google Scholar 

Wei, T., Hwan Jung, J. & Scott, T. F. Dynamic covalent assembly of peptoid-based ladder oligomers by vernier templating. J. Am. Chem. Soc. 137, 14 (2015).

Article  Google Scholar 

Porel, M. & Alabi, C. A. Sequence-defined polymers via orthogonal allyl acrylamide building blocks. J. Am. Chem. Soc. 136, 13162–13165 (2014).

Article  CAS  PubMed  Google Scholar 

Solleder, S. C. & Meier, M. A. R. Sequence-controlled polymers sequence control in polymer chemistry through the passerini three-component reaction. Angew. Chem. Int. Edn Engl. 53, 711–714 (2014).

Article  CAS  Google Scholar 

Wang, S., Tao, Y., Wang, J., Tao, Y. & Wang, X. A versatile strategy for the synthesis of sequence-defined peptoids with side-chain and backbone diversity via amino acid building blocks. Chem. Sci. 10, 1531–1538 (2019).

PubMed  Google Scholar 

Yan, J.-J., Wang, D., Wu, D.-C. & You, Y.-Z. Synthesis of sequence-ordered polymers via sequential addition of monomers in one pot. Chem. Commun. 49, 6057 (2013).

Article  CAS  Google Scholar 

Tao, Y., Tao, Y., Tao, Y. & Tao, H. Ugi reaction of amino acids: from facile synthesis of polypeptoids to sequence-defined macromolecules. Macromol. Rapid Commun. 42, 2000515 (2021).

Article